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Updated: Sep 8, 2025

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Rhodium-Catalyzed Z-Alkenyl 1,3-Migration

Xue-Mei Huang1, Si-Qi Xiong1, Zi-Xin Ye1

  • 1School of Chemistry and Chemical Engineering, Southwest University, Chongqing 400715, P. R. China.

Organic Letters
|August 1, 2025
PubMed
Summary

This study introduces a rhodium-catalyzed Z-alkenyl 1,3-migration for synthesizing unsaturated ketones. It achieves selective C(sp3)-C(Z-alkenyl) bond cleavage under mild conditions.

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