High-Precision 3D Doping of Fused Silica Glass Derived from Nanocomposites
- Richard Prediger 1, Sebastian Kluck 1, Leonhard Hambitzer 1, Bastian E Rapp 1,2,3,4, Silvio Tisato 2, Josephine N Häberlein 5,3, Dorothea Helmer 2,3,4, Frederik Kotz-Helmer 1,4
- 1Laboratory of Process Engineering, NeptunLab, Department of Microsystems Engineering (IMTEK), University of Freiburg, 79110, Freiburg, Germany.
- 2Freiburg Materials Research Center (FMF), University of Freiburg, 79104, Freiburg, Germany.
- 3Freiburg Center for Interactive Materials and Bioinspired Technologies, University of Freiburg, 79110, Freiburg, Germany.
- 4Glassomer GmbH, In den Kirchenmatten 54, 79110, Freiburg, Germany.
- 5Electrochemical Energy Systems, IMTEK, Department of Microsystems Engineering (IMTEK), University of Freiburg, 79110, Freiburg, Germany.
- 0Laboratory of Process Engineering, NeptunLab, Department of Microsystems Engineering (IMTEK), University of Freiburg, 79110, Freiburg, Germany.
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View abstract on PubMed
Summary
This summary is machine-generated.This study introduces a novel 3D printing method for precise dopant integration in glass, enabling customized optical and material properties for advanced applications.
Area Of Science
- Materials Science
- Optical Engineering
- Additive Manufacturing
Background
- Conventional glass production results in uniform properties, limiting localized modifications.
- Advanced applications require glasses with spatially tailored optical, mechanical, and thermal characteristics.
Purpose Of The Study
- To develop a high-resolution 3D dopant integration technique for glasses.
- To enable precise control over material properties within 3D-shaped glass structures.
Main Methods
- Fabrication of a porous glass matrix via 3D printing or injection molding.
- Volumetric 3D printing (e.g., computed axial lithography, two-photon lithography) for dopant precursor infiltration.
- Permanent dopant integration through a final sintering step.
Main Results
- Achieved micron-resolution 3D dopant integration within the glass matrix.
- Demonstrated selective modification of color, luminescence, and refractive index.
- Successfully integrated dopants including Ti<sup>4+</sup>, Co<sup>2+</sup>, Eu<sup>3+</sup>, and Tb<sup>3+</sup>.
Conclusions
- The novel lithographic approach enables spatially resolved property modifications in 3D-shaped glasses.
- This technique opens possibilities for integrated optics, photonics, anti-counterfeiting, and information storage.
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