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Inductively Coupled Plasma Atomic Emission Spectroscopy: Instrumentation01:26

Inductively Coupled Plasma Atomic Emission Spectroscopy: Instrumentation

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Inductively coupled plasma (ICP) is the common plasma source used in atomic emission spectroscopy (AES), a technique that detects and analyzes various elements in a sample. This method is often called inductively coupled plasma atomic emission spectroscopy (ICP-AES).
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A conventional Raman spectrophotometer includes a laser source, a sample holding system, a wavelength selector, and a detector.
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The absorbance of UV and visible (UV–visible) radiations is measured using a UV–visible spectrophotometer. Deuterium lamps, which emit UV radiation, and tungsten lamps, which produce radiation in the visible region, are used as light sources in UV–visible spectrophotometers. A monochromator or prism is used for diffraction grating, i.e., to split the incoming radiation into different wavelengths. A system of slits is used to focus the desired wavelength on the sample cell.
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NMR spectrometers consist of a strong magnet, a radiofrequency transmitter, and a detector attached to a computer console for recording spectra of samples containing NMR-active nuclei. In first-generation NMR instruments called continuous-wave spectrometers, the resonance frequencies of the nuclei are determined by frequency-sweep or field-sweep methods. The magnetic field strength is fixed and the rf signal is swept in the former, while the radiofrequency signal is fixed and the magnetic field...
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The instrumentation of atomic emission spectrometry (AES) involves various components, including atomization devices that convert samples into gas-phase atoms and ions. There are two main types of atomization devices: continuous and discrete atomizers.  Continuous atomizers, like plasmas and flames, introduce samples in a constant stream, while discrete atomizers inject individual samples using syringes or autosamplers. The most common discrete atomizer is the electrothermal atomizer.
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There are two main infrared (IR) spectrophotometers: dispersive IR spectrometers and Fourier transform infrared (FTIR) spectrometers. In a dispersive IR spectrometer, a beam of infrared radiation produced by a hot wire is divided into two parallel equal-intensity beams using mirrors. One beam passes through the sample, while another is a reference beam. The beams then move through the monochromator, which separates the radiations into a continuous spectrum of different frequencies. The...
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Single-pixel computational spectrometer based on nonlinear spectrum modulation.

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    This study introduces a new computational spectrometer that uses a modulated light source for active illumination. This compact, low-cost device achieves high spectral resolution, comparable to commercial systems, for object spectrum reconstruction.

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    Area of Science:

    • Optics and Photonics
    • Spectroscopy
    • Nonlinear Optics

    Background:

    • Computational spectroscopy often relies on ambient light, limiting applications requiring active illumination.
    • Existing systems struggle with effective light source spectrum modulation, hindering performance.

    Purpose of the Study:

    • To develop a novel computational spectrometer with integrated light-source spectrum modulation.
    • To offer a compact, low-cost alternative to conventional spectrometers for active illumination scenarios.

    Main Methods:

    • Utilized polarization-induced nonlinear spectrum modulation for light source control.
    • Employed wavelength multiplexing and compressed sensing for spectral reconstruction.
    • Managed polarization-induced nonlinear phase and pump power for periodic spectrum evolution.

    Main Results:

    • Achieved a minimum spectral resolution of 0.2 nm, comparable to commercial spectrometers.
    • Demonstrated successful reconstruction of sparse and non-sparse spectra via simulation and experiment.
    • Operated effectively within a spectral range of 1000 nm to 1100 nm.

    Conclusions:

    • The novel spectrometer enables active illumination computational spectroscopy with high performance.
    • The system's compact and low-cost design makes it suitable for diverse applications.
    • Polarization-induced nonlinear spectrum modulation is a viable technique for advanced spectroscopic systems.