Efficient Tetracycline Hydrochloride Degradation by Urchin-Like Structured MoS₂@CoFe₂O₄ Derived from Steel Pickling...

Steel pickling sludge serves as a valuable iron source for synthesizing Fe-based catalysts in heterogeneous advanced oxidation processes (AOPs). Here, MoS₂@CoFe₂O₄ catalyst derived from steel pickling sludge was prepared via a facile solvothermal approach and utilized to activate peroxymonosulfate (PMS) for tetracycline hydrochloride (TCH) degradation. Comprehensive characterization using scanning electron microscopy (SEM)-energy dispersive spectrometer (EDS), X-ray photoelectron spectroscopy (XPS), and X-ray diffraction (XRD) confirmed the supported microstructure, composition, and crystalline structure of the catalyst. Key operational parameters-including catalyst dosage, PMS concentration, and initial solution pH-were systematically optimized, achieving 81% degradation efficiency within 30 min. Quenching experiments and electron paramagnetic resonance (EPR) analysis revealed SO₄^∙- as the primary oxidative species, while the catalyst maintained high stability and reusability across cycles. TCH degradation primarily occurs through hydroxylation, decarbonylation, ring-opening, and oxidation reactions. This study presents a cost-effective strategy for transforming steel pickling sludge into a high-performance Fe-based catalyst, demonstrating its potential for practical AOP applications.