Synchronous Improvement of Mechanical and Room-Temperature Damping Performance in Light-Weight Polyurethane...

In order to address vibration and noise challenges in modern industry while satisfying the lightweighting requirements for aerospace and transportation applications, the development of polymer elastomers integrating both lightweight and high-damping properties holds substantial significance. This study developed polyurethane (PU) with optimized damping and mechanical properties at room temperature through monomer composition optimization. Hollow glass microspheres (HGMs) were introduced into the PU matrix to increase stiffness and reduce density, though this resulted in decreased tensile strength (Rm) and loss factor (tanδ). To further improve mechanical and damping properties, we applied a carbon coating to the surface of the HGMs to optimize the interface between the HGMs and the PU matrix, and systematically investigated the energy dissipation and load-bearing behavior of PU composites. The effect of enhanced interface damping of HGM@C/PU resulted in broadening of the effective damping temperature range (tanδ ≥ 0.3) and higher maximum loss factor (tanδ_max) compared to HGM/PU at equivalent filler loading. The tensile and dynamic properties significantly improved due to optimized interfacial adhesion. In PU composites reinforced with 10 wt% HGM and HGM@C, a 46.8% improvement in Rm and 11.0% improvement in tanδ_max occurred after carbon coating. According to acoustic testing, average transmission loss of HGM/PU and HGM@C/PU with the same filler content showed a difference of 0.3-0.5 dB in 500-6300 Hz, confirming that the hollow structure of the HGMs was preserved during carbon coating.