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Long-lived room-temperature phosphorescent carbon dot-based composites for anti-counterfeiting and information
Yanni Jie1, Jiang Yan1, Zengbo Fan1
1School of Materials Science & Engineering, Shaanxi Key Laboratory of Green Preparation and Functionalization for Inorganic Materials, Shaanxi University of Science and Technology, Xi'an, 710021, China. jieyanni@sust.edu.cn.
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Here, we report a simple solvent-free strategy for preparing blue-green room-temperature phosphorescent carbon dot-based composites by heat treating terephthalic acid (TPA) and boric acid (BA) at 250 °C. The designed composites (CDs@B2O3) exhibit an ultralong lifetime of 1.768 s, lasting over 25 s to the naked eye, concurrently with a photoluminescence quantum yield (PLQY) of 33.2%. Furthermore, the CDs@B2O3 composites have been applied to anti-counterfeiting, information encryption, and delayed lighting. This work provides a novel strategy for designing metal-free room-temperature phosphorescent carbon dots with sustained luminescence, revealing promising potential for advanced applications.
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