Correlation between thermal stability and β relaxation of La-Ce-Al-Co-Ga bulk metallic glasses

  • 0Center for Advanced Structural Materials, State Key Laboratory of Metastable Materials Science and Technology, Yanshan University, Qinhuangdao 066004, China.

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Summary

This summary is machine-generated.

Improving the thermal stability of metallic glasses is crucial. This study reveals key correlations between beta relaxation processes and thermal stability, offering strategies to enhance glass performance.

Area Of Science

  • Materials Science
  • Condensed Matter Physics

Background

  • Metallic glasses exhibit thermal instability, limiting their applications and processing.
  • Enhancing thermal stability is a critical research area for metallic glasses.

Purpose Of The Study

  • To investigate the relationship between beta relaxation and thermal stability in metallic glasses.
  • To identify correlations between beta relaxation parameters and thermal properties like glass transition temperature and supercooled liquid region width.

Main Methods

  • Studied a [(La0.7Ce0.3)65Al10Co25]100-xGax model system.
  • Analyzed dynamic mechanical properties to probe relaxation processes.
  • Correlated relaxation intensities, temperatures, and activation energies with thermal stability indicators.

Main Results

  • Positive correlation found between the ratio of beta to alpha relaxation intensity (E″β/E″α) and glass transition temperature (Tg).
  • Positive correlation observed between the ratio of beta to alpha relaxation temperature (Tβ/Tα) and the supercooled liquid region width (ΔTx).
  • Negative correlation identified between ΔTx and beta relaxation activation energy (Eβ).

Conclusions

  • Established three key relationships linking beta relaxation dynamics to the thermal stability of metallic glasses.
  • Demonstrated that regulating beta relaxation is a viable strategy to enhance thermal stability.
  • Findings deepen the understanding of factors governing glass stability and offer practical implications for material design.

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