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Internal Encapsulation for Perovskite Solar Cells
Guangyu Zhang1, Runnan Yu1, Zhuoxu Liu1
1State Key Laboratory of Chemical Resource Engineering, Beijing Advanced Innovation Center for Soft Matter Science and Engineering, Beijing University of Chemical Technology, Beijing, 100029, China.
Chemsuschem
|August 19, 2025
Summary
Internal encapsulation enhances perovskite solar cell (PSC) stability by passivating defects and inhibiting ion migration. This review details internal encapsulation strategies for improved photovoltaic device performance and commercialization.
Area of Science:
- Materials Science
- Renewable Energy
- Photovoltaics
Background:
- Perovskite solar cells (PSCs) offer high efficiency and low-cost fabrication.
- Their commercialization is limited by inherent instability issues.
- External encapsulation has limitations in protecting PSCs.
Purpose of the Study:
- To systematically review internal encapsulation strategies for perovskite solar cells.
- To elucidate the mechanisms and material design principles of internal encapsulation.
- To discuss the application effects, challenges, and future prospects of this technology.
Main Methods:
- Review of internal encapsulation techniques including macrocyclic chelators, crosslinking molecules, and functional polymers.
- Analysis of material design and cross-device layer integration.
- Evaluation of application effects on perovskite stability and performance.
Main Results:
- Internal encapsulation effectively enhances PSC stability by addressing defect passivation and ion migration.
- Specific materials and design principles are identified for improved device longevity.
- Internal encapsulation complements external methods for superior protection.
Conclusions:
- Internal encapsulation is a key strategy for overcoming perovskite solar cell instability.
- Further research into material design and application is crucial for commercial viability.
- This approach holds significant promise for next-generation photovoltaic technologies.

