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Recent Progress and Developments in Transition Metal Dichalcogenides: Synthesis, Properties, and Applications
Shilpa Thakur1, Pandian Mannu2, Chung-Li Dong2
1School of Applied Engineering, University of Petroleum and Energy Studies (UPES), Bidholi, Dehradun, Uttarakhand, 248007, India.
None:
The breakthrough discovery of graphene has directed attention toward 2D structural materials like silicene, phosphorene, transition metal dichalcogenides (TMDCs), and hexagonal boron nitride. Recently, TMDCs have been investigated extensively, attributable to their exceptional chemical and physical properties. In particular, few-layer or monolayer TMDCs have numerous advantages, for example, weak interlayer van der Waals force, direct band gap, abundant marginal active sites, and large interlayer spacing, which make them extensively used in gas sensing, energy conversion, energy storage, catalysis, and optoelectronic devices. This review provides an outline of the inherent characteristics of TMDCs and their current fabrication methods, including hydro/solvothermal, physical vapor deposition (PVD), chemical vapor deposition, and other techniques, such as chemical synthesis and physical vapor methods. Moreover, the application of TMDCs in various fields has also been discussed thoroughly. Finally, it also highlights the challenges and future directions, including the necessity for improved synthesis methods, understanding their stability, and investigation into new applications. This review reveals the synthesis, structures, properties, modifications, applications, and perceptions of TMDCs.
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Properties of Transition Metals
Crystal Field Theory - Octahedral Complexes
To explain the observed behavior of transition metal complexes (such as colors), a model involving electrostatic interactions between the electrons from the ligands and the electrons in the unhybridized d orbitals of the central metal atom has been developed. This electrostatic model is crystal field theory (CFT). It helps to understand, interpret, and predict the colors, magnetic behavior, and some structures of coordination compounds of transition metals.
CFT focuses on...
Colors and Magnetism
When atoms or molecules absorb light at the proper frequency, their electrons are excited to higher-energy orbitals. For many main group atoms and molecules, the absorbed photons are in the ultraviolet range of the electromagnetic spectrum, which cannot be detected by the human eye. For coordination compounds, the energy difference between the d orbitals often allows photons in the visible range to be absorbed and emitted, which is seen as colors by the human eye.