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Updated: Sep 10, 2025

Synchrotron X-ray Microdiffraction and Fluorescence Imaging of Mineral and Rock Samples
Published on: June 19, 2018
VORTEX (Variscite origin recognition technology X-ray based) Data. A European geoarchaeological green phosphate
Daniel Sánchez-Gómez1, José Ángel Garrido-Cordero2, José María Martínez-Blanes3
1UNIARQ, Centro de Arqueologia da Universidade de Lisboa, 1600-214, Lisbon, Portugal.
This study introduces a new data-driven framework using portable X-ray fluorescence (p-XRF) and machine learning (ML) to trace the origin of archaeological artifacts. The method accurately identifies the geological source of green phosphate minerals, aiding in understanding prehistoric trade networks.
Area of Science:
- Geoarchaeology
- Archaeological Science
- Materials Science
Background:
- Prehistoric mining of phosphate minerals in Iberia is well-documented.
- Understanding the provenance of archaeological artifacts is crucial for reconstructing past social networks and trade routes.
- Existing methods for artifact provenance can be destructive or lack precision.
Purpose of the Study:
- To develop and validate a data-driven framework for determining the provenance of archaeological artifacts using elemental composition.
- To integrate portable X-ray fluorescence (p-XRF) analysis with machine learning (ML) for artifact sourcing.
- To create a comprehensive dataset of green phosphate mineral compositions from Iberian deposits.
Main Methods:
- Compositional analysis of 1778 geoarchaeological samples using portable X-ray fluorescence (p-XRF).
- Mineralogical analysis of a subset of samples (N=249) using X-ray diffraction (XRD).
- Development and application of a machine learning model trained on elemental composition data to predict artifact provenance.
Main Results:
- A robust framework integrating p-XRF and ML was established for accurate artifact provenance determination.
- Elemental composition data (atomic percentages of Al-Th) and mineralogical data were systematically collected and presented.
- The model successfully traced the origin of 571 variscite beads from various archaeological sites.
Conclusions:
- The developed framework offers a non-destructive and accurate method for sourcing archaeological artifacts.
- This dataset and methodology have significant potential for future research in artifact provenance and social network analysis.
- The study provides valuable geochemical and mineralogical data for Iberian green phosphate deposits.
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