Related Experiment Video
Updated: Sep 10, 2025
Facile Synthesis of Colloidal Lead Halide Perovskite Nanoplatelets via Ligand-Assisted Reprecipitation
Published on: October 1, 2019
Modulating magneto-photoluminescence effects in 3D lead halide perovskites via halide-component dependent Rashba
Zhen Wang1, Jifan Xie1, Jiayu Zheng2
1School of Integrated Circuits, Chongqing University of Posts and Telecommunications, Chongqing 400065, China.
Abstract:
Three-dimensional lead halide perovskites (3D LHPs) exhibit giant Rashba spin-orbit coupling (SOC) due to their inherent lattice asymmetry and heavy-metal composition; yet, the impact of Rashba SOC on the luminescence dynamic of 3D LHPs remains debated. Here, we utilize the magneto-photoluminescence (Magneto-PL) effects as an effective tool to reveal the underlying spin-related opto-physical process in 3D LHPs. We find that the magneto-PL effects of 3D LHPs CH3NH3Pb(Br/I/IxCl1-x)3 thin films are negative and tunable at room temperature, indicating the remarkable suppression of their PL emission intensity by magnetic fields. Moreover, the largest magneto-PL magnitude of -3.60% is realized in CH3NH3PbIxCl3-x thin film at a magnetic field strength of ±1 T; oppositely, in CH3NH3PbI3 thin film, it is merely -0.75%. Combining magneto-optical spectroscopy and crystallographic analysis of 3D LHP thin films, we attribute this phenomenon to the interplay of the Rashba SOC-driven spin mixing and Zeeman splitting between dark singlet and bright triplet excitons, promoting spin conversion from dark excitonic states to bright states. In addition, we demonstrate that the Rashba SOC is tunable and has a direct relationship with the crystalline phase transition and grain size by modifying halide-components, which leads to the halide-components dependent magneto-PL effects in 3D LHP thin films. This work paves the way for improving the luminescence property of opto-spintronics materials via modulating Rashba SOC.
Related Concept Videos
03:02Colors and Magnetism
When atoms or molecules absorb light at the proper frequency, their electrons are excited to higher-energy orbitals. For many main group atoms and molecules, the absorbed photons are in the ultraviolet range of the electromagnetic spectrum, which cannot be detected by the human eye. For coordination compounds, the energy difference between the d orbitals often allows photons in the visible range to be absorbed and emitted, which is seen as colors by the human...
01:27π Electron Effects on Chemical Shift: Overview
02:42Valence Bond Theory