Membrane Fouling Control and Treatment Performance Using Coagulation-Tubular Ceramic Membrane with Concentrate...

A comparative study was conducted to investigate membrane fouling control and treatment performance using natural surface water as the feed source. The evaluated processes included: (1) direct filtration-tubular ceramic membrane (DF-TCM, control); (2) coagulation-tubular ceramic membrane (C-TCM); and (3) coagulation-tubular ceramic membrane with concentrate recycling (C-TCM-CR). Experimental results demonstrated that under constant flux operation at 75 L/(m²·h) for 8 h, the C-TCM-CR process reduced the transmembrane pressure (TMP) increase by 83% and 35% compared to DF-TCM and C-TCM, respectively. Floc size distribution analysis and cake layer characterization revealed that the C-TCM-CR process enhanced coagulation efficiency and formed high-porosity cake layers on membrane surfaces, thereby mitigating fouling development. Notably, the coagulation-assisted processes demonstrated improved organic matter removal, with 13%, 10%, and 10% enhancement in COD_Mn, UV₂₅₄, and medium molecular weight organics (2000-10,000 Da) removal compared to DF-TCM, along with a moderate enhancement in fluorescent substances removal efficiency. All three processes achieved over 99% turbidity removal efficiency, as the ceramic membranes demonstrate excellent filtration performance.