Multilayer Graphene Nanoshells from Biomass for Fast-Charge, Long-Cycle-Life and Low-Temperature Li-Ion Anodes

Graphene nanoshells (MGNS) were prepared from cellulose, a sustainable biopolymer. Different sizes/morphologies were obtained by simply changing the metal catalyst salt in the synthesis. The MGNS were shown to reversibly cycle Li-ions by an intercalation mechanism similar to graphite. The reversible capacity of each MGNS prepared from different metal salts correlates well to its degree of 3-D graphitic order. The small size of the MGNS allows for short Li diffusion distances and very rapid charging, obtaining a 20% charge in 36 s (100 C rate). The unique spherical structure provides stable cycling, losing only 3.8% capacity over 900 cycles, and eliminates exfoliation that occurs when cycling graphite in propylene carbonate (PC), an inexpensive, environmentally friendly electrolyte. This enables cycling in a PC-only solvent-based electrolyte, with stable cycling and high capacities at temperatures as low as -35 °C. At this very low temperature, 95% of the RT reversible capacity is retained, with only a modest charge potential increase due to the increase in viscosity of the solvent.