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P-N junction01:11

P-N junction

673
A p-n junction is formed when p-type and n-type semiconductor materials are joined together. At the interface of the p-n junction, holes from the p-side and electrons from the n-side begin to diffuse into the opposite sides due to the concentration gradient. This diffusion of carriers leads to a region around the junction where there are no free charge carriers, known as the depletion region. The charge density within the depletion region for the n-side and p-side can be described by the...
673
Biasing of P-N Junction01:16

Biasing of P-N Junction

839
The operation of a p-n junction diode involves various biasing conditions, including forward bias, reverse bias, and equilibrium.
In equilibrium, no external voltage is applied across the p-n junction. The depletion region is formed at the junction interface due to the diffusion of carriers, which leaves behind charged dopants, acceptors on the p-side, and donors on the n-side. These immobile charges create an electric field that prevents further diffusion of carriers. The related energy band...
839
Photoelectric Effect02:26

Photoelectric Effect

30.5K
When light of a particular wavelength strikes a metal surface, electrons are emitted. This is called the photoelectric effect. The minimum frequency of light that can cause such emission of electrons is called the threshold frequency, which is specific to the metal. Light with a frequency lower than the threshold frequency, even if it is of high intensity, cannot initiate the emission of electrons. However, when the frequency is higher than the threshold value, the number of electrons ejected...
30.5K
Metal-Semiconductor Junctions01:24

Metal-Semiconductor Junctions

505
The contact of metal and semiconductor can lead to the formation of a junction with either Schottky or Ohmic behavior.
Schottky Barriers
Schottky barriers arise when a metal with a work function (Φm) contacts a semiconductor with a different work function (Φs). Initially, electrons transfer until the Fermi levels of the metal and semiconductor align at equilibrium. For instance, if Φm > Φs, the semiconductor Fermi level is higher than the metal's before contact. The...
505
Schottky Barrier Diode01:27

Schottky Barrier Diode

486
Schottky barrier diodes are specialized semiconductor devices characterized by their unique construction. This construction involves combining a metal layer with a moderately doped n-type semiconductor material. This combination leads to the formation of a Schottky barrier, a pivotal element that defines the diode's operational characteristics. The core functionality of Schottky barrier diodes is their capacity to allow current to flow in only one direction due to their distinctive...
486
Bipolar Junction Transistor01:22

Bipolar Junction Transistor

913
Bipolar Junction Transistors (BJTs) are essential elements in electronic circuits, playing a crucial role in the functionality of amplifiers, memories, and microprocessors. These transistors can be designed as NPN or PNP based on their doping patterns. They consist of three layers: the emitter, base, and collector. The configuration of these layers and their respective doping levels—with N-type or P-type impurities—define the transistor's type and its operational...
913

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Related Experiment Video

Updated: Sep 9, 2025

Developing High Performance GaP/Si Heterojunction Solar Cells
10:31

Developing High Performance GaP/Si Heterojunction Solar Cells

Published on: November 16, 2018

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Self-Powered High-Performance WS2 Photodetector via a Monolithic p-i-n Homojunction.

Jehwan Park1, Younghyun You1,2, Donggyu Lee1

  • 1Department of Chemical and Biological Engineering, Seoul National University, Seoul 08826, Republic of Korea.

Nano Letters
|September 2, 2025
PubMed
Summary

Researchers developed a self-powered photodetector using tungsten disulfide (WS2) with tunable doping. This breakthrough enables precise control over carrier concentrations in 2D materials for advanced optoelectronic devices.

Keywords:
dopinghomojunctionself-powered photodetectortransition-metal dichalcogenides

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Area of Science:

  • Materials Science
  • Condensed Matter Physics
  • Nanotechnology

Background:

  • Lateral homojunction photodetectors (PDs) in 2D transition-metal dichalcogenides (TMDs) show promise for high responsivity and fast response.
  • Achieving controlled carrier concentrations in TMDs remains a significant challenge for device implementation.

Purpose of the Study:

  • To demonstrate a high-performance, self-powered, monolithic lateral p-i-n homojunction photodetector using multilayer WS2.
  • To establish a method for tunable, multilevel compensation doping in WS2 via controlled oxidation.

Main Methods:

  • Utilized time-controlled and region-selective ultraviolet (UV)/ozone oxidation to form WOX on WS2.
  • Characterized the oxidation process, observing distinct phases of WOX formation and WS2 transformation.
  • Employed photocurrent mapping to confirm the lateral p-i-n homojunction structure.

Main Results:

  • Achieved a responsivity of 471 mA/W at 530 nm in the self-powered PD.
  • Demonstrated a high rejection ratio of 200 and fast response times of approximately 4.5 ms.
  • Successfully controlled free carrier concentrations in WS2 through a novel oxidation technique.

Conclusions:

  • The developed WOX formation process enables precise control over carrier doping in WS2.
  • This work paves the way for versatile monolithic homojunction optoelectronic devices based on TMDs.