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Preparation of Contiguous Bisaziridines for Regioselective Ring-Opening Reactions
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Solvent-dependent reactivity of azo-BF2 switches.

Qingkai Qi1,2, Heyifei Fu1, Lingya Peng3

  • 1Department of Chemistry, Dartmouth College Hanover New Hampshire 03755 USA ivan.aprahamian@dartmouth.edu.

Chemical Science
|September 2, 2025
PubMed
Summary

New azo-BF2 photoswitches with naphthalene modifications show tunable NIR light response. Solvent choice dictates reactivity, leading to either boron difluoride hydrazone fluorophores or solvolysis, crucial for developing advanced molecular devices.

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