Enhanced Strain Properties in KNN-Based Lead-free Piezoelectric Multilayer Actuators by Low-Temperature Texture
Jingkai Nie1,2, Ning Qiu3, Shicheng Zhang1,2
1China Electric Power Research Institute, Beijing 100192, China.
ACS Omega
|September 8, 2025
Summary
Lead-free piezoelectric ceramics offer an eco-friendly alternative for multilayer piezoelectric actuators (MLAs). This study enhances KNN-based ceramics via texturing and CuO addition, achieving high strain performance for advanced actuator applications.
Area of Science:
- Materials Science
- Ceramic Engineering
- Solid State Physics
Background:
- Growing demand for lead-free alternatives to traditional lead-based piezoelectric materials.
- Need for high-performance piezoelectric ceramics in multilayer piezoelectric actuators (MLAs).
- Challenges in improving piezoelectric properties while maintaining high Curie temperatures and environmental friendliness.
Purpose of the Study:
- To develop and investigate lead-free KNN-based ceramics for MLA applications.
- To enhance piezoelectric properties through advanced texturing techniques and sintering aids.
- To evaluate the performance of fabricated KNN-based multilayer piezoelectric actuators.
Main Methods:
- Utilized a compositional system: 0.96-(Na0.5K0.5)-(Nb0.965Sb0.035)-O3-0.01CaZrO3-0.03-(K0.5Bi0.5HfO3) (KNNS-KBH-CZ).
- Incorporated 0.2% CuO as a sintering aid to improve ceramic properties.
- Employed the TGG texturing technique combined with stacked element cofiring for fabricating MLAs.
- Investigated the piezoelectric properties and strain performance of the developed materials.
Main Results:
- Achieved a high texturing degree of 75% in KNNS-KBH-CZ/CuO ceramics.
- Demonstrated excellent strain performance: 0.14% strain and 466 pm/V d33*.
- Observed high performance under a low electric field of 3 kV/mm.
Conclusions:
- The developed KNN-based textured ceramics exhibit significant potential for lead-free multilayer piezoelectric actuators.
- The combination of texturing and CuO addition effectively enhances piezoelectric properties.
- These findings support the application of KNN-based piezoceramics as sustainable alternatives in actuator technology.


