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Developing Photosensitizer-Cobaloxime Hybrids for Solar-Driven H2 Production in Aqueous Aerobic Conditions
Published on: October 5, 2019
Mechanochemical grafting enables fluorescein-sensitized cobalt-based MOF for visible-light-driven hydrogen evolution
Taya Ko Saothayanun1, Phirom Boun1, Yollada Inchongkol1
1School of Energy Science and Engineering (ESE), Vidyasirimedhi Institute of Science and Technology (VISTEC), 555 Moo 1 Payupnai, Wangchan, Rayong 21210, Thailand. Taya.S_s17@vistec.ac.th.
Abstract:
A rapid mechanochemical approach was developed to covalently graft an isothiocyanate dye onto an amino-functionalized metal-organic framework (MOF), enabling visible-light-driven hydrogen production via dye sensitization. This method offers a greener and more efficient alternative to conventional solution-based dye-labeling techniques that typically require excessive solvents and elevated temperatures.
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