Nanomaterial Functionalized Carbon Fiber-Reinforced Composites with Energy Storage Capabilities

We have demonstrated the fabrication of laminate composites with functional features to demonstrate energy storage capabilities. The present study investigates the surface modification of carbon fibers by coating dual materials of reduced graphene oxide (rGO) and cellulose-based activated carbon to enhance their energy storage capacitance for the development of structural supercapacitors. The dual coating on carbon fibers enabled a near 210-fold improvement in surface area, surpassing that of pristine carbon fibers. This formed a highly porous graphene network with activated carbon, resulting in a well-connected fiber-graphene-activated carbon network on carbon fibers. The electrochemical supercapacitor, fabricated from surface-functionalized carbon fibers, provides the best performance, with a specific capacitance of 172 F g^-1 in an aqueous electrolyte. Furthermore, the symmetrical structural supercapacitor (SSSC) device delivered a specific capacitance of 227 mF g^-1 across a wide potential window of 6 V. The electrochemical stability of the SSSC device was validated by a high capacitance retention of 97.3% over 10,000 cycles. Additionally, the study showcased the practical application of this technology by successfully illuminating an LED using the proof-of-concept SSSC device with G-aC/CF electrodes. Overall, the findings of this study highlight the potential of carbon fiber composites as a promising hybrid material, offering both structural integrity and a functional performance suitable for aerospace and automobile applications.