Effect of Heat Treatment on Microstructures and Mechanical Properties of TC4 Alloys Prepared by Selective Laser...

The reduced ductility caused by the brittle needle-like α' martensite limits the application of TC4 alloys produced by selective laser melting (SLM). Appropriate heat treatment can improve the microstructures and properties of SLM-fabricated TC4 alloys. In this work, SLM-fabricated TC4 alloys underwent stress relief annealing at 600 °C and high-temperature annealing at 800 °C. The effects of heat treatment temperature on phase composition, microstructural morphology, grain orientation, and mechanical properties were investigated. Meanwhile, the microstructural evolution and fracture mechanisms during the heat treatment process were analyzed. The results indicate that after annealing at 600 °C, the needle-like α' phase transforms into elongated α, and nano-β phase increases. When annealed at 800 °C, the α' phase completely transforms into a more stable lath-shaped α phase and a short rod-shaped β phase, with the nano-β phase disappearing. The texture orientation gradually shifts from <0001> towards <01-10>, where slip systems are more active. Additionally, heat treatment promotes the transition of grain boundaries to high-angle grain boundaries, thereby alleviating stress concentration and enhancing solid-solution strengthening. After heat treatment, the ultimate tensile strength of the material slightly decreases, but the elongation significantly increases. As the annealing temperature increased, the elongation (EL) improved from 5.22% to 11.43%. Following high-temperature annealing at 800 °C, necking and larger dimples appear on the fracture surface, and the fracture mechanism shifts from a mixed brittle-ductile fracture to a ductile fracture. This work provides a theoretical basis for improving the microstructures and properties of SLM-fabricated TC4 alloys through heat treatment.