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Updated: Jun 11, 2026

The Synthesis, Characterization and Reactivity of a Series of Ruthenium N-triphosPh Complexes
Published on: April 10, 2015
Synthesis and characterization of rhena-phenalenyl complexes
Lei Li1, Bingjie Fu1, Yue Zhao1
1School of Chemistry, Dalian University of Technology, Dalian 116024, P. R. China. baiwei@dlut.edu.cn.
None:
Metallaaromatics are attractive due to their special structures and properties. In this work, the first metalla-phenalenyl complexes containing CReC units were obtained from ReCl3(PMePh2)3 and 1,8-diethynylnaphthalene compounds. The delocalized rhenaphenalenyl structure exhibits good planarity. DFT studies show that the 3MR rhenacyclopropene units are σ-aromatic, while the 6MR rhenacycle is nonaromatic. Though the rhenapolycycle is stable, it can be oxidized with one 3MR broken, resulting in another rhenaphenalenyl structure.
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