Spatiotemporal mapping of alloy mesostructure dynamics via multimodal coherent X-ray diffraction imaging

Understanding mesoscale structural dynamics of precipitation-strengthened alloys is essential for optimizing the mechanical performances of these alloys. Herein, we establish a multimodal coherent X-ray diffraction imaging framework for spatiotemporal mapping of mesoscale structural dynamics in precipitation-strengthened alloys. As a demonstrative application, we visualized the structural evolution in Mg₉₇Zn₁Gd₂ during isothermal annealing at 700 K, revealing real-time dynamics of nucleation, growth, and coarsening. Ptychographic reconstruction enabled imaging of microstructural transformations across a wide field of view (~100 μm²) with temporal resolution spanning several hours. We observed decomposition of (Mg, Zn)₃Gd and concurrent precipitation and coarsening of long-period stacking ordered phases. To resolve local dynamics at finer spatiotemporal scales, we combined dynamic coherent diffraction imaging with X-ray photon correlation spectroscopy, targeting selected regions (~10 μm²) with time resolution down to tens of seconds. This approach revealed the rapid formation of nanoscale precipitates within 10 s after heating, followed by coarsening over several hundred seconds. Additionally, we applied optical flow analysis-a computational method to track motion patterns-to visualize and quantify the nucleation, growth, and coarsening kinetics. The abovementioned findings demonstrate the capability of in situ coherent X-ray techniques to acquire the real-time evolutions of mesoscale structures in complex materials. Our methodology offers a robust framework for investigating dynamic phenomena in diverse material systems, including metals, polymers, and functional nanomaterials, under realistic thermal or mechanical conditions.