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From Molecules to Materials: Engineering New Ionic Liquid Crystals Through Halogen Bonding
Published on: March 24, 2018
Organic Halogen Substitution-Driven Halogen Bonding Induces Polar 3D Supramolecular Framework and
Ming-Chang Wang1, Jia-Jia Li1, Yan Chen2
1Fujian Provincial Key Laboratory of Advanced Materials Oriented Chemical Engineering, College of Chemistry and Materials Science, Fujian Normal University, Fuzhou 350007, China.
None:
The development of nonlinear optical (NLO) crystals with strong second-harmonic-generation (SHG) efficiency, large birefringence, and wide bandgaps is crucial for next-generation ultraviolet photonics. Here we report two new organic-inorganic metal halides, HPyXB(OH)2CdCl3 (X = Cl, Br; Py = pyridyl), that demonstrate how halogen substitution on organic ligands can effectively tune crystal symmetry and optical performance. Both compounds feature one-dimensional [CdCl3]∞- chains constructed from face-sharing CdCl6 octahedra. The chlorine-containing HPyClB(OH)2CdCl3 crystallizes in the centrosymmetric space group P1̅, forming a two-dimensional supramolecular structure with antiparallel π-conjugated cations. It shows a large birefringence of 0.22 at 546 nm and a wide bandgap of 4.08 eV. In contrast, bromine substitution induces C-Br···O halogen bonding and O-H···O hydrogen bonding, which drive HPyBrB(OH)2CdCl3 into a polar three-dimensional supramolecular framework in the noncentrosymmetric space group Pna21. This symmetry breaking unlocks a phase-matchable SHG efficiency of 1.0× KH2PO4 while retaining a large birefringence (0.16 at 546 nm) and a wide bandgap (3.81 eV). These results highlight halogen substitution as an effective strategy for designing high-performance ultraviolet NLO crystals.
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