Flexible Hydrazone-Linked Covalent Organic Frameworks With Enhanced Emission and Selective Nitroaromatic Sensing
Wanyi Zhao1, Ning Chen2, Yuqing Li1
1Laboratory of Preparation and Applications of Environmental Friendly Materials (Jilin Normal University), Ministry of Education, Jilin Normal University, Changchun, China.
Novel covalent organic frameworks (COFs) with flexible backbones overcome aggregation-caused quenching (ACQ) for enhanced solid-state luminescence. These materials show promise for sensitive nitroaromatic compound detection and optoelectronics.
Area of Science:
- Materials Science
- Chemistry
- Nanotechnology
Background:
- Covalent organic frameworks (COFs) possess ordered π-conjugated structures beneficial for solid-state luminescence.
- Aggregation-caused quenching (ACQ) significantly limits the photoluminescence efficiency of many COFs in the solid state.
- Developing COFs with suppressed ACQ is crucial for practical applications in optoelectronics and sensing.
Purpose of the Study:
- To design and synthesize novel hydrazone-linked COFs with inherent structural flexibility.
- To investigate the mitigation of ACQ effects in solid-state COF luminescence.
- To explore the application of these COFs in the sensitive and selective detection of nitroaromatic compounds.
Main Methods:
- Rational design and synthesis of two hydrazone-linked COFs featuring flexible vertex units.
- Characterization of the structural, photophysical, and sensing properties of the synthesized COFs.
- Evaluation of fluorescence quenching mechanisms upon interaction with nitroaromatic compounds.
Main Results:
- The synthesized COFs exhibit strong solid-state green emission with high photoluminescence quantum yields (up to 20%).
- Structural flexibility effectively suppresses aggregation-caused quenching (ACQ).
- The COFs demonstrate highly sensitive and selective fluorescence-based detection of 2,4,6-trinitrophenol (TNP) via noncovalent interactions.
Conclusions:
- Incorporating flexible units into COF backbones is a viable strategy to enhance solid-state luminescence and overcome ACQ.
- The developed COFs show significant potential for advanced chemical sensing applications, particularly for nitroaromatic explosives.
- This work broadens the scope of COFs in optoelectronics and high-performance sensing platforms.
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