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Weak Host Interactions Induced Thermal Transport Properties of Metal Halide Perovskites Deviating from the Rattling
Yu Wu1, Linxuan Ji2, Shuming Zeng3
1Advanced Thermal Management Technology and Functional Materials Laboratory, Ministry of Education Key Laboratory of NSLSCS, School of Energy and Mechanical Engineering, Nanjing Normal University, Nanjing 210023, P. R. China.
Abstract:
The low-frequency phonon branches of metal halide perovskites typically exhibit the characteristic of hardening with the increase of the cation mass, which leads to an anomalous thermal transport phenomenon. However, the underlying physical mechanism is not yet understood. Here, we theoretically compare the thermal transport properties of A2SnI6 (A = K, Rb, and Cs) perovskites. The thermal transport in perovskites is widely explained using the rattling model, where "guest" cations inside the metal halide framework act as "rattlers", but this fails to explain the following phenomenon: The low-frequency phonon branch of A2SnI6 perovskites is insensitive to the mass of the A+ cation and strongly correlated with the interaction of the A+ cation with the I- anion in the octahedral structures. The failure of the rattling model stems mainly from the weak interactions between the octahedral structures. We find that this weak interaction is prevalent in other metal halide perovskites. By developing a new spring model, we successfully explain the thermal transport behavior in A2SnI6 perovskites. Our work gives new insights into the thermal transport mechanism in metal halide perovskites, which has a guiding significance for designing extremely low thermal conductivity materials.
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