Developing a Low-Cost Device for Estimating Air-Water ΔpCO₂ in Coastal Environments

The ocean is one of the world's largest anthropogenic carbon dioxide (CO₂) sinks, but closing the carbon budget is logistically difficult and expensive, and uncertainties in carbon fluxes and reservoirs remain. One specific challenge is that measuring the CO₂ flux at the air-sea interface usually requires costly sensors or analyzers (USD > 30,000), which can limit observational capacity. Our group has developed and validated a low-cost ΔpCO₂ system, able to measure both pCO₂^water and pCO₂^air, for USD ~1400 to combat this limitation. The device is equipped with Internet of Things (IoT) capabilities and built around a USD ~100 pCO₂ K30 sensor at its core. Our Sensor for the Exchange of Atmospheric CO₂ with Water (SEACOW) may be placed in an observational network with traditional pCO₂ sensors or ∆pCO₂ sensors to extend the spatial coverage and resolution of monitoring systems. After calibration, the SEACOW reports atmospheric pCO₂ measurements that are within 2-3% of the measurements made with a calibrated LI-COR LI-850. We also demonstrate the SEACOW's ability to capture diel pCO₂ cycling in seagrass, provide recommendations for SEACOW field deployments, and provide additional technical specifications for the SEACOW and for the K30 itself (e.g., air- and water-side 99.3% response time; 5.7 and 29.6 min, respectively).