Path Selective Photoinduced Energy and Electron Transfer in a Bis(acridinium-Zn(II) Porphyrin)-tetrapyridyl Porphyrin...

The 1:1 complex of a bis(acridinium-Zn(II)porphyrin) host and a tetrapyridyl free-base porphyrin guest shows a remarkable interplay of energy and electron transfer (eT) processes, finely tuned by the solvent polarity or the selection of the photoexcited component. A more polar environment (CH₂Cl₂) favors uncommon parallel intramolecular and intermolecular eT processes, while in an apolar solvent (toluene) the intermolecular eT process is hampered. Notably, the apolar environment also enables a rare energy transfer process from the porphyrin guest toward the charge-transfer emissive state of the tweezer host. In total, no less than four different excited states were probed, which can be sketched by an inverted pyramid diagram highlighting directional path selection.