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Activation of colloidal patchy particle networks.

H J Jonas1, N Oikonomeas2, P Schall2

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This summary is machine-generated.

Adding active particles to colloidal gels creates dynamic structures. Increasing activity leads to void-rich networks, fragmented clusters, or phase separation, impacting bond dynamics.

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Area of Science:

  • Soft Matter Physics
  • Colloidal Science
  • Non-equilibrium Systems

Background:

  • Active physical gels, like biological cytoskeletons, exhibit complex non-equilibrium physics due to continuous energy input.
  • Self-assembled colloidal architectures offer controllable experimental models for studying these active gels.

Purpose of the Study:

  • To numerically investigate the impact of self-propelled colloids (active Brownian particles) on network-forming colloidal dispersions.
  • To explore the structural and dynamical responses of these active physical gels across varying levels of particle activity.

Main Methods:

  • Numerical simulations of a colloidal dispersion with di-patch and tri-patch particles.
  • Introduction of active Brownian particles (self-propelled colloids) into the system.
  • Analysis of structural changes (e.g., void formation, fragmentation, phase separation) and bond probability.

Main Results:

  • Low activity: formation of inhomogeneous, void-rich structures.
  • Medium activity: network fragmentation into chain clusters and broad local density distributions.
  • High activity: emergence of motility-induced phase separation.
  • Structural changes are linked to alterations in bond probability, affecting bond formation and breakage rates.

Conclusions:

  • The activity of embedded particles significantly alters the structure and dynamics of colloidal gels.
  • The observed responses (void-rich, fragmented, or phase-separated states) are tunable by controlling particle activity.
  • Findings provide insights into the physics of active matter and self-assembled soft materials.