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Updated: Jan 16, 2026
Construction and Systematical Symmetric Studies of a Series of Supramolecular Clusters with Binary or Ternary Ammonium Triphenylacetates
Published on: February 15, 2016
Hydrogen Bond Reformation in Tetracarboxylic Acid-Based Organic Frameworks with Square Lattice Topology
1Division of Chemistry, Graduate School of Engineering Science, The University of Osaka, 1-3 Machikaneyama, Toyonaka, Osaka, 560-8531, Japan.
Abstract:
The weak and reversible nature of hydrogen bonds endows porous materials with structural flexibility. In this article, we highlight structural transformations involving the cleavage and reformation of hydrogen bonds-termed H-bond reformation. To enable control over H-bond reformation through molecular design, we examine and discuss key structural features. Particular attention is given to tetracarboxylic acids bearing 4,4'-dicarboxy-o-terphenyl moieties as scaffolds for inducing H-bond reformation. These insights are expected to guide the rational design of dynamic porous materials with tunable properties and stimuli-responsive behavior.
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