Mechanically Robust and Conductive Gelatin/Glucose Hydrogels Enabled by the Hofmeister Effect for Flexible Strain...

Conductive hydrogels are attractive for flexible electronics; however, achieving high mechanical strength and conductivity simultaneously remains challenging. Herein, we present a facile strategy to fabricate a tough and conductive hydrogel by immersing a physically crosslinked gelatin/glucose hydrogel in an aqueous sodium citrate. The introduction of sodium citrate induced multiple physical interactions via the Hofmeister effect, which synergistically reinforced the hydrogel network. The resulting hydrogel exhibited excellent mechanical properties, with a fracture strength of 2.7 MPa, a fracture strain of 932%, and a toughness of 9.5 MJ/m³. Moreover, the incorporation of free ions imparted excellent ionic conductivity of 0.97 S/m. A resistive strain sensor based on this hydrogel showed a linear and sensitive response over a wide strain range and stable performance under repeated loading-unloading cycles. These features enabled accurate and reliable monitoring of various human movements. This work offers an effective strategy for designing hydrogels with both high strength and conductivity for flexible and wearable electronics.