Related Experiment Video
Updated: Jan 16, 2026

Construction and Systematical Symmetric Studies of a Series of Supramolecular Clusters with Binary or Ternary Ammonium Triphenylacetates
Published on: February 15, 2016
Geometric Analysis and Experimental Studies of Hexachiral Structures
Julian Plewa1, Małgorzata Płońska1, Kamil Feliksik1
1Faculty of Science and Technology, Institute of Materials Engineering, University of Silesia in Katowice, 75 Pułku Piechoty Str., 41-500 Chorzów, Poland.
Chiral metamaterials with hexachiral structures show auxetic behavior, contracting under compression. Their negative Poisson
Area of Science:
- Metamaterials Science
- Materials Physics
- Mechanical Engineering
Background:
- Chiral metamaterials possess inherent asymmetry, preventing overlap with their mirror images.
- Hexachiral structures, composed of nodes and ligaments, are a type of chiral metamaterial.
- Auxetic materials exhibit a negative Poisson's ratio, expanding when stretched and contracting when compressed.
Purpose of the Study:
- To investigate the auxetic properties of hexachiral metamaterial structures.
- To determine the Poisson's ratio of these structures under various compression conditions.
- To explore the relationship between structure geometry and auxetic performance.
Main Methods:
- Theoretical analysis and geometric calculations of hexachiral structures.
- Experimental fabrication of metamaterial structures using 3D printed nodes and ligaments.
- Uniaxial and multi-directional compression testing of the fabricated structures.
Main Results:
- Hexachiral structures demonstrated a negative Poisson's ratio approaching -1 under compression.
- The Poisson's ratio was found to be independent of compression degree for uniaxial loading.
- Structure deformation varied across different parts during uniaxial compression.
- Multi-directional compression also resulted in a negative Poisson's ratio near -1, dependent on compression degree.
Conclusions:
- Hexachiral metamaterials exhibit significant auxetic properties with a Poisson's ratio close to -1.
- The number of unit cells influences the Poisson's ratio, approaching theoretical values in larger structures.
- These structures can function as elastic energy reservoirs, showing auxetic behavior under multi-directional stress.
Related Concept Videos
Stereoisomerism of Cyclic Compounds
Conformations of Cyclohexane
The chair form is the most stable and derives its name from its resemblance to the “easy chair.” In the chair conformation, two carbon atoms are arranged out-of-plane — one above and one below, minimizing the torsional strain. In the chair form, the bond angle is very close to the ideal...
Chair Conformation of Cyclohexane
The hydrogen atoms linked to carbons are arranged in two different axial and equatorial orientations to achieve this...
Prochirality
VSEPR Theory and the Basic Shapes
Radicals: Electronic Structure and Geometry
Accordingly, the structure of a trivalent radical lies between the geometries of carbocations and carbanions. An sp2-hybridized carbocation is trigonal planar, while an sp3-hybridized carbanion is trigonal pyramidal. Here, the difference in geometry is...

