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Updated: Jan 16, 2026

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Published on: June 20, 2019
Liquid Crystalline Block Copolymers for Advanced Applications: A Review
Maryam Safari1, Jules A W Harings1
1Aachen Maastricht Institute for Biobased Materials (AMIBM), Faculty of Science and Engineering, Maastricht University, Urmonderbaan 22, 6167RD Geleen, The Netherlands.
None:
Liquid crystalline block copolymers (LCBCPs) have emerged as an adaptable hybrid class at the intersection of self-assembling block copolymers and liquid crystalline ordering, producing multi-tiered architectures that can be finely programmed for multifunctional performance. This review surveys recent advances in their structure-property relationships and highlights applications spanning nanotechnology, biomedical systems, flexible photonics, stimuli-responsive, energy storage, and soft robotics. Particular emphasis is placed on how molecular design enables precise tuning of structural, optical, mechanical, and stimuli-responsive functions, positioning LCBCPs as strong candidates for next-generation functional materials. We also discuss current challenges, including scalability, phase control, and advanced characterization, and outline promising research directions to accelerate their translation from laboratory concepts to real-world technologies.
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