Eco-Friendly Synthesis of Silver-Cellulose Nanocomposite Adsorbent from Agricultural Residues for Binary Dye System...

This work reports a one-step, green synthesis of silver-micro cellulose nanocomposite (Ag@Ce NCs) using Azadirachta indica A. Juss leaf extract to load micro-cellulose isolated from peanut shells with silver nanoparticles, followed by comprehensive physicochemical characterization (FTIR, TEM, EDX-SEM, zeta potential, and XRD). The composite has pH_PZC ≈ 5.0 and was tested for simultaneous removal of methylene blue (MB) and safranin O (SO) under batch conditions across various pH levels, doses, contact times, initial concentrations, ionic strengths, and temperatures. The high removal efficiencies observed at pH 10 for MB and 6.0 for SO. The adsorption reached the maximum at 45 min before partially declining, indicating reversible binding on saturated surfaces. Isotherm study favored the Langmuir model, with similar affinities (K_L ≈ 0.106, and 0.110 L/mg) and monolayer capacities of 17.99 mg/g for MB and 14.90 mg/g for SO, suggesting non-selective competition on uniform sites. Kinetic data fitted the pseudo-second-order model, while thermodynamic analysis indicated mainly exothermic and physisorption interactions. Higher ionic strength reduced removal efficiency (at 1.0 M NaCl, %RE ≈ 33-48%), highlighting salt sensitivity typical of electrostatic attraction. The adsorbent maintained about 90% of its initial performance after five adsorption-desorption cycles in 0.1 M H₂SO₄, indicating excellent reusability. Overall, Ag@Ce NCs provide an inexpensive, eco-friendly, and reuseable platform for treating binary mixtures of cationic dyes.