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Synthesis of Hypervalent Iodonium Alkynyl Triflates for the Application of Generating Cyanocarbenes
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Harnessing Phenonium Ions in Synthesis.

Robert J Mayer1, David Lebœuf2

  • 1School of Natural Sciences, Department Chemie, Technical University of Munich, 85748, Garching, Germany.

Angewandte Chemie (International Ed. in English)
|September 29, 2025
PubMed
Summary

Recent advances enable the controlled generation and application of phenonium ions in synthesis. This review highlights strategies for harnessing these reactive intermediates, overcoming previous limitations in their use.

Keywords:
HypernucleofugeKineticsPhenonium ionReaction mechanismsRearrangement

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