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Consider an external electric field propagating through a homogeneous medium. When the electric field crosses the surface boundary of the medium, it undergoes a discontinuity. The electric field can be resolved into normal and tangential components. The amount by which the field changes at any boundary is given by the difference between the field components above and below the surface boundary.
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Related Experiment Video

Updated: Jun 27, 2026

Characterization of Full Set Material Constants and Their Temperature Dependence for Piezoelectric Materials Using Resonant Ultrasound Spectroscopy
07:44

Characterization of Full Set Material Constants and Their Temperature Dependence for Piezoelectric Materials Using Resonant Ultrasound Spectroscopy

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Negative Piezoelectric Response in YS2.

Jinzhe Han1, Erjun Kan1

  • 1Department of Applied Physics and MIIT Key Laboratory of Semiconductor Microstructure and Quantum Sensing, Nanjing University of Science and Technology, Nanjing 210094, People's Republic of China.

ACS Omega
|October 6, 2025
PubMed
Summary
This summary is machine-generated.

The YS₂ monolayer exhibits negative piezoelectric properties, offering insights into magnetic and piezoelectric materials. This research explores the relationship between structure and magnetism in transition-metal dichalcogenides.

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Area of Science:

  • Condensed Matter Physics
  • Materials Science
  • Computational Chemistry

Background:

  • Transition-metal dichalcogenides (TMDs) are a class of materials with diverse electronic and magnetic properties.
  • Understanding the interplay between magnetism and piezoelectricity in 2D materials is crucial for next-generation electronic devices.

Purpose of the Study:

  • Investigate the magnetic and piezoelectric characteristics of YX₂ (X = S, Se, Te) monolayers.
  • Analyze the electronic band structures to understand the origin of observed properties.
  • Explore the relationship between structural configurations and p-orbital ferromagnetism.

Main Methods:

  • First-principles calculations were employed to study YX₂ monolayers and bilayers.
  • Spin-polarized electronic band structures were computed using the HSE hybrid functional and PBE + U methods.
  • Analysis of Born effective charges to understand piezoelectric response.

Main Results:

  • The YS₂ monolayer, in its 1H structure, displays a negative in-plane piezoelectric coefficient (d₁₁ = -2.53 × 10⁻¹⁰ C/m).
  • A substantial Born effective charge was identified as the cause for the negative piezoelectric response along the armchair direction.
  • Ferromagnetic behavior linked to p-orbital interactions was observed.

Conclusions:

  • The study reveals a complex correlation between the structural arrangement and p-orbital ferromagnetism in TMDs.
  • The findings highlight the potential of YS₂ as a promising material for piezoelectric applications.
  • This research provides foundational insights for designing novel magnetic and piezoelectric 2D materials.