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Types of Step-Growth Polymers: Polyesters01:20

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The introduction of polyesters has brought major development to the textile industry. The wrinkle-free behavior of polyester blends has eliminated the need for starching and ironing clothes.
Polyesters are commonly prepared from terephthalic acid and ethylene glycol; the crude product is known as poly(ethylene terephthalate) or PET. However, polyesters are synthesized industrially by transesterification of dimethyl terephthalate with ethylene glycol at 150 °C. The two reactants and the polymer...
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Deep eutectic solvent as a solution for polyester/cotton textile recycling.

Nika Depope1, Al Depope2, Vasiliki-Maria Archodoulaki3

  • 1Institute of Chemical, Environmental and Bioscience Engineering, TU Wien, Getreidemarkt 9/166, 1060 Vienna, Austria; JR Centre for Recovery Strategies for Textiles (ReSTex), Institute of Chemical, Environmental and Bioscience Engineering, TU Wien, Getreidemarkt 9/166, 1060 Vienna, Austria.

Waste Management (New York, N.Y.)
|October 9, 2025
PubMed
Summary

This study introduces a sustainable method for recycling polyester/cotton blends using deep eutectic solvents (DESs). The process efficiently recovers both PET and cotton fibers, offering a greener alternative for textile waste management.

Keywords:
Deep eutectic solventsPET dissolutionPolyester/cottonPolymer recoveryTextile recycling

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Area of Science:

  • Materials Science
  • Chemical Engineering
  • Environmental Science

Background:

  • Global textile production, dominated by polyester (PET) and cotton (CO), generates significant waste.
  • There is a growing demand for sustainable recycling solutions in the textile industry.
  • Current recycling methods often involve toxic chemicals or are inefficient for blended fabrics.

Purpose of the Study:

  • To develop an innovative and sustainable method for recycling polyester/cotton (PET/CO) blends.
  • To utilize hydrophobic deep eutectic solvents (DESs) for efficient and selective separation of PET and CO.
  • To assess the quality and properties of the recovered materials for potential reuse.

Main Methods:

  • Dissolution of PET/CO blends using hydrophobic deep eutectic solvents (DESs).
  • Selective recovery of PET and CO components.
  • Characterization of recovered materials using Scanning Electron Microscopy (SEM), Differential Scanning Calorimetry (DSC), Thermogravimetric Analysis (TGA), Attenuated Total Reflectance Fourier-Transform Infrared Spectroscopy (ATR-FTIR), and mechanical testing.

Main Results:

  • Complete dissolution of PET within 5 minutes using DESs.
  • High recovery yields: 97% for PET and 100% for CO.
  • SEM confirmed no morphological damage to cotton fibers.
  • DSC, TGA, and ATR-FTIR indicated no significant chemical or thermal degradation of recovered polymers.
  • Recovered cotton showed a decrease in tenacity (28%) and elongation (34%) but remained within usable ranges.

Conclusions:

  • The proposed DES-based process offers an efficient, rapid, and sustainable method for recycling PET/CO textile blends.
  • This method avoids toxic chemicals and recovers both polymers with properties suitable for manufacturing.
  • The process presents a viable solution for reducing textile waste and promoting a circular economy in the fashion industry.