Related Experiment Video
Updated: Aug 5, 2026

A Technique to Functionalize and Self-assemble Macroscopic Nanoparticle-ligand Monolayer Films onto Template-free Substrates
Published on: May 9, 2014
Macroscopic Transition Metal Dichalcogenide Monolayers from Gold-Tape Exfoliation Retain Intrinsic Properties
Nicholas Olsen1, Sunggun Yoon2, Madisen Holbrook2,3
1Department of Chemistry, Columbia University, New York, New York 10027, United States.
Abstract:
The "gold-tape" exfoliation technique can deterministically exfoliate macroscopic transition metal dichalcogenide (TMD) monolayers from bulk single crystals, overcoming limitations of the widely used "Scotch-tape" method, but concerns over the quality of the large-area monolayers remain. Here we introduce a critical step improving the gold-tape method by eliminating a previously unknown polymer residue layer on the TMD surface. The resulting pristine and millimeter-scale TMD monolayers exhibit defect density, charge carrier mobility, and excitonic properties intrinsic to the parent crystal. Imaging, transport, and spectroscopy on length scales spanning 6 orders of magnitude demonstrate the viability of gold-exfoliated TMD monolayers for the deterministic fabrication of high-performance van der Waals devices, including moiré interfaces.
More Related Videos
08:12Ohmic Contact Fabrication Using a Focused-ion Beam Technique and Electrical Characterization for Layer Semiconductor Nanostructures
Published on: December 5, 2015
10:41Preparation of Liquid-exfoliated Transition Metal Dichalcogenide Nanosheets with Controlled Size and Thickness: A State of the Art Protocol
Published on: December 20, 2016
Related Concept Videos
Bonding in Metals
Metallic Solids
All metallic solids exhibit high thermal and electrical conductivity, metallic luster, and malleability. Many...
Properties of Transition Metals
Properties of Organometallic Compounds
Complexation Equilibria: Factors Influencing Stability of Complexes
Metal-Semiconductor Junctions
Schottky Barriers
Schottky barriers arise when a metal with a work function (Φm) contacts a semiconductor with a different work function (Φs). Initially, electrons transfer until the Fermi levels of the metal and semiconductor align at equilibrium. For instance, if Φm > Φs, the semiconductor Fermi level is higher than the metal's before contact. The semiconductor's...