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Precipitation and coprecipitation methods can be used to separate a mixture of ions in a solution. In qualitative inorganic analysis, ions that form sparingly soluble precipitates with the same reagent are separated based on the differences in solubility products. For example, consider the separation of Cu(II) and Fe(II) ions by precipitation as insoluble sulfides. First, copper(II) sulfide is precipitated by the addition of acidic H2S, where the dissociation of H2S is suppressed. Adding H2S...
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Metal ions can be separated from one another by complexation with organic ligands–the chelating agent– to form uncharged chelates. Here, the chelating agent must contain hydrophobic groups and behave as a weak acid, losing a proton to bind with the metal. Since most organic ligands used in this process are insoluble or undergo oxidation in the aqueous phase, the chelating agent is initially added to the organic phase and extracted into the aqueous phase. The metal-ligand complex is...
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Colloidal solids are solid particles suspended in solution. They are usually negatively charged, attracting a compact primary layer of positively charged ions, which attract more counterions to form an electrical double layer. Electrostatic repulsion between the charged double layers prevents the particles from colliding, stabilizing the colloids. These solids are often undesirable because they can contain toxins that are difficult to remove. Coagulation is a technique that helps aggregate and...
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Color in Coordination Complexes
When atoms or molecules absorb light at the proper frequency, their electrons are excited to higher-energy orbitals. For many main group atoms and molecules, the absorbed photons are in the ultraviolet range of the electromagnetic spectrum, which cannot be detected by the human eye. For coordination compounds, the energy difference between the d orbitals often allows photons in the visible range to be absorbed and emitted, which is seen as colors by the human...
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Electrodeposition is a technique used to separate an analyte from interferents by electrochemical processes. Here, the analyte is a metal ion that can be deposited on an electrode immersed in the sample solution. The electrochemical setup consists of an anode and a cathode. When an electric current is applied to the setup, oxidation occurs at the anode. At the cathode, which consists of a large metal surface, metal ions undergo reduction and deposit onto the surface.
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Kinetics describes the rate and path by which a reaction occurs. In contrast, thermodynamics deals with state functions and describes the properties, behavior, and components of a system. It is not concerned with the path taken by the process and cannot address the rate at which a reaction occurs. Although it does provide information about what can happen during a reaction process, it does not describe the detailed steps of what appears on an atomic or a molecular level. On the other hand,...
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Explainable machine learning framework for predicting cobalt ion removal by natural hematite.

Arwa Saad1, Abdelmoty M Ahmed2, Mohamed Shaban3

  • 1Faculty of Computer Science, Nahda University, Beni Suef, Egypt.

Scientific Reports
|October 10, 2025
PubMed
Summary

Natural hematite effectively removes cobalt ions (Co2+) from water, achieving 89.7% removal. A hybrid artificial intelligence model accurately predicts removal efficiency, highlighting temperature and contact time as key factors.

Keywords:
Adsorption experimentsExplainable artificial intelligenceHeavy metal removalMachine learningWater treatment

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Area of Science:

  • Environmental Science
  • Materials Science
  • Artificial Intelligence

Background:

  • Cobalt contamination in aquatic environments poses significant environmental and public health risks.
  • Developing efficient and sustainable methods for cobalt ion removal is crucial.

Purpose of the Study:

  • To investigate natural hematite (α-Fe2O3) as a cost-effective adsorbent for cobalt ion (Co2+) removal.
  • To develop and validate a hybrid artificial intelligence framework for predicting cobalt adsorption efficiency.

Main Methods:

  • Batch adsorption experiments were conducted to assess cobalt removal under varying conditions (contact time, adsorbent dosage, initial concentration, temperature).
  • A contrastive learning XGBoost model was employed for accurate prediction of cobalt removal efficiency.
  • Statistical analyses and Shapley Additive Explanations (SHAP) were used to identify influential parameters.

Main Results:

  • Natural hematite achieved a maximum cobalt removal efficiency of 89.7% at 100 ppm.
  • Temperature and contact time were identified as the most significant factors influencing cobalt removal (p < 0.01).
  • The XGBoost model demonstrated high predictive accuracy (R² = 0.987) and robustness.

Conclusions:

  • Natural hematite is a promising, economical, and sustainable adsorbent for cobalt ion removal from aquatic systems.
  • The developed hybrid AI framework provides accurate and reliable predictions for cobalt adsorption.
  • Understanding the influence of operational parameters like temperature and contact time is key for optimizing cobalt removal processes.