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A battery is a galvanic cell that is used as a source of electrical power for specific applications. Modern batteries exist in a multitude of forms to accommodate various applications, from tiny button batteries such as those that power wristwatches to the very large batteries used to supply backup energy to municipal power grids. Some batteries are designed for single-use applications and cannot be recharged (primary cells), while others are based on conveniently reversible cell reactions that...

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Solid-state Graft Copolymer Electrolytes for Lithium Battery Applications
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Composition-Controlled Cathode Protective Layer via Powder-Atomic Layer Deposition for All-Solid-State Batteries.

Kyu Moon Kwon1, Dae Ho Kim1, Ha Yeon Kwon1

  • 1Department of Materials Science and Chemical Engineering, Hanyang University, Ansan, 15588, South Korea.

Advanced Science (Weinheim, Baden-Wurttemberg, Germany)
|October 14, 2025
PubMed
Summary
This summary is machine-generated.

Controlling protective layer composition in all-solid-state batteries (ASSBs) is key. Tailoring lithium zirconium oxide layers on cathode active materials enhances ionic and electronic conductivity, improving battery performance and stability.

Keywords:
all‐solid‐state batteriesatomic layer depositioncathode protective layerlithium zirconium oxidepowder ALD

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Area of Science:

  • Materials Science
  • Electrochemistry
  • Battery Technology

Background:

  • Stabilizing interfaces between cathode active materials (CAMs) and sulfide solid electrolytes is crucial for all-solid-state batteries (ASSBs).
  • Controlling ionic and electronic conductivities of protective layers on CAMs is essential for interface stabilization.

Purpose of the Study:

  • To investigate the effect of varying lithium zirconium oxide compositions on protective layers for CAMs.
  • To establish a quantitative correlation between protective layer composition and ASSB performance.

Main Methods:

  • Atomic layer deposition (ALD) using O3 to grow lithium zirconium oxide layers on LiNi0.8Co0.1Mn0.1O2.
  • Characterization of ionic and electronic conductivities of the protective layers.
  • Electrochemical performance testing of coated and uncoated CAMs in ASSBs.

Main Results:

  • Ionic conductivity of lithium zirconium oxide layers reached 2.20 × 10^-7 S cm^-1 at 25 °C.
  • Electronic conductivity ranged from 10^-10 to 10^-7 S cm^-1, varying with composition.
  • Coated CAMs showed a 6.7% increase in initial Coulombic efficiency and a 43% increase in capacity retention compared to uncoated ones.

Conclusions:

  • Protective layer composition significantly impacts ionic and electronic transport properties.
  • Composition control of protective layers is a critical strategy for interfacial engineering in sulfide-based ASSBs.
  • Optimized protective layers enhance the electrochemical performance and long-term stability of ASSBs.