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Updated: Jan 15, 2026

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Molecular Entanglement and Electrospinnability of Biopolymers
Published on: September 3, 2014
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Physical Characterization of Multiwire Polystyrene Produced by Electrospinning Technique
Lorenzo Torrisi1, Letteria Silipigni1, Alfio Torrisi2
1Dipartimento MIFT, Università di Messina, Viale F.S. d'Alcontres 31, 98166 Messina, Italy.
Polymers
|October 16, 2025
Summary
Electrospun multiwire polystyrene (PS) shows enhanced hydrophobicity and dielectric properties, especially with graphene oxide (GO) nanoparticles. These findings suggest potential applications for advanced materials.
Area of Science:
- Materials Science
- Polymer Science
Background:
- Polystyrene (PS) is a widely used polymer with diverse applications.
- Understanding the morphology and properties of nanostructured polymers is crucial for developing advanced materials.
Purpose of the Study:
- To characterize the morphology and optical properties of electrospun multiwire polystyrene (PS).
- To compare the properties of multiwire PS with bulk PS and multiwire PS containing graphene oxide (GO) nanoparticles (NPs).
- To investigate the potential applications of the produced multiwire PS.
Main Methods:
- Electrospinning technique for producing multiwire PS.
- Physical characterization including morphology analysis.
- Optical property measurements (IR, UV-Visible transmittance and absorbance).
- Wetting angle measurements to assess surface hydrophobicity.
- Dielectric permittivity measurements as a function of frequency.
Main Results:
- Multiwire PS exhibited enhanced hydrophobicity, with wetting angles up to approximately 144°.
- The hydrophobic nature was further increased by embedding graphene oxide (GO) nanoparticles.
- Optical properties in the IR and UV-Visible regions were analyzed.
- Polystyrene demonstrated optimal dielectric properties, with permittivity measured across a range of frequencies.
Conclusions:
- Electrospun multiwire PS, particularly with GO NPs, offers significantly enhanced hydrophobicity.
- The material possesses favorable dielectric properties, indicating its suitability for electronic applications.
- The study highlights the potential of multiwire PS for various technological applications.

