Development of a Validated Rate-Based Model for CO₂ Absorption in Aqueous 2‑Amino-2-methyl-1-propanol and Piperazine...

In this work, we developed a new e-NRTL thermodynamic framework for CO₂ absorption in aqueous mixtures of 2-amino-2-methyl-1-propanol (AMP) and piperazine (PZ) in Aspen Plus. The e-NRTL AMP/PZ/H₂O/CO₂ model was fitted on experimental data covering a range of AMP concentration from 12 to 48 mass % and PZ concentration from 2 to 26 mass %, temperature from 20 to 160 °C and CO₂ loading from 0 to 1.03 $\frac{mo{l}_{C{O}_2}}{mo{l}_{AMP}+mo{l}_{PZ}}$ . The model predicts the CO₂ solubility, as partial pressure of CO₂, over aqueous AMP/PZ solutions within an absolute average relative deviation (AARD) of 26.3%, the total pressure of the system with an AARD value of 7.0%, the heat of absorption of CO₂ with an AARD value of 10.2%, and the estimated free CO₂ concentration with an AARD value of 13.1%. The model gives a good representation of liquid speciation as a function of the CO₂ loading and amine concentration. The model shows good predictions of the CO₂ solubility over aqueous AMP/PZ solutions at relevant absorber, stripper and water wash amine concentrations and temperatures. The developed e-NRTL model, in combination with mass transfer and CO₂ absorption kinetics modeling, is validated with two pilot campaigns: one at the University of Kaiserslautern and one at the Technology Centre of Mongstad. The developed rate-based model predicts the CO₂ capture, rich loading, and specific reboiler duty within 5% absolute average relative deviation.