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Updated: Jan 14, 2026

Probing the Structure and Dynamics of Interfacial Water with Scanning Tunneling Microscopy and Spectroscopy
Published on: May 27, 2018
Frontier interfacial water properties characterization and applications
Ying-Ru Qiu1, Wei Peng2, Runze Zhang1
1College of Materials, State Key Laboratory of Physical Chemistry of Solid Surfaces, iChEM, College of Chemistry and Chemical Engineering, College of Energy, School of Life Sciences, College of Physical Science and Technology, and Discipline of Intelligent Instrument and Equipment, Xiamen University, Xiamen 361005, China.
Abstract:
Interfacial water is a unique form of water existing at the phase boundary. Due to its distinctive physical and chemical properties, it is significantly different from the ordinary bulk water and plays a crucial role in various scientific and technological fields. A deep understanding of interfacial water is expected to bring revolutionary applications in fields ranging from energy conversion to bionic intelligence. In this review, we start with clarification of the fundamental differences between interfacial water and bulk water, and comprehensively examine the structures, electrical properties, and hydrodynamics of interfacial water. Then, the principles and functions of advanced characterization techniques in revealing the moleculer-scale behavior of interfacial water are discussed. Experimental and computational advances in interfacial water research are reviewed to elucidate the key role of interfacial water in catalysis, energy storage, biological processes, and hydropower technologies, with the interaction between mechanistic insights and practical breakthroughs being emphasized. We further outline the prospects for advancing basic science and transformative applications, positioning interfacial water research as the cornerstone of the next generation of innovation.
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