Optimized Synthesis and Device Integration of Long 17-Atom-Wide Armchair Graphene Nanoribbons

Seventeen-carbon-atom-wide armchair graphene nanoribbons (17-AGNRs) are promising candidates for high-performance electronic devices due to their narrow electronic bandgap. Atomic precision in edge structure and width control is achieved through a bottom-up on-surface synthesis (OSS) approach from tailored molecular precursors in ultrahigh vacuum (UHV). This synthetic protocol must be optimized to meet the structural requirements for device integration, with the ribbon length being the most critical parameter. Here, we report optimized OSS conditions that produce 17-AGNRs with an average length of ∼17 nm. This length enhancement is achieved through a gradual temperature ramping during an extended annealing period, combined with a template-like effect driven by monomer assembly at high surface coverage. The resulting 17-AGNRs are comprehensively characterized in UHV by using scanning probe techniques and Raman spectroscopy. Raman measurements following substrate transfer enabled the characterization of GNRs' length distribution on the device substrate and confirmed their stability under ambient conditions and harsh chemical environments, including acid vapors and etchants. The increased length and ambient stability of the 17-AGNRs led to their reliable integration into device architectures. As a proof of concept, we integrate 17-AGNRs into field-effect transistors (FETs) with graphene electrodes and confirm that electronic transport occurs through the GNRs. This work demonstrates the feasibility of integrating narrow bandgap GNRs into functional devices and contributes to advancing the development of carbon-based nanoelectronics.