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Updated: Jan 14, 2026

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Controlling the Size, Shape and Stability of Supramolecular Polymers in Water
Published on: August 2, 2012
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Size-matched supramolecular assembly between an asymmetric Anderson-type polyoxometalate hybrid and
Chun-Yan Liu1, Yun-Jing Mu1, Wu-Ji Chen1
1State Key Laboratory of Chemical Resource Engineering, Beijing University of Chemical Technology, Beijing 100029, P. R. China. linchg@mail.buct.edu.cn.
Abstract:
We report here the supramolecular assembly between a new asymmetric polyoxometalate hybrid and α-/γ-CDs, which leads to novel pseudo-rotaxane and poly-pseudo-rotaxane structures that have been thoroughly characterized in solution and in the solid state by adopting various techniques, including NMR, ESI-TOF-MS, ITC and single-crystal X-ray diffraction.

