A Hierarchically Porous Amino-MOFs Loaded AgPd Nanoparticles for Efficient Photothermal Semi-Hydrogenation Catalysis
Chao Liu1, Gang-Gang Chang1, Ting-Ting Luo1
1State key Laboratory of Advanced Glass Materials, School of Chemistry, Chemical Engineering and Life Science, State Key Laboratory of Advanced Technology for Materials Synthesis and Processing, Wuhan University of Technology, Wuhan, Hubei, 430070, China.
None:
Herein, a hierarchically porous AgPd/HP-UiO-66-NH2 is fabricated for photothermal catalysis, in which AgPd NPs can not only show photothermal conversion ability, but also promote the high chemo-selectivity of Pd sites due to its synergistic effect. Furthermore, the hierarchically porous amino-MOFs enable this catalyst to response for visible light thanks to the introduction of amino group and reduce the mass transfer resistance becuase of its porous structure. Therefore, AgPd/HP-UiO-66-NH2 shows excellent catalytic performance under illumination and room temperature.
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