Recent Advances in Homogeneous Catalysis with Platinum Group Pincer Complexes: Hydrogen-Mediated Transformations and
Juan S Serrano-García1, Andrés Amaya-Flórez1, Jordi R-Galindo1
1Instituto de Química, Universidad Nacional Autónoma de México, Ciudad de México, CP, México.
Abstract:
The use of pincer complexes based on platinum group metals is undoubtedly one of the most widely applied strategies today for the design of homogeneous catalysts in various chemical transformations, owing to their high stability and facile functionalization. This review aims to cover the advances achieved so far in homogeneous catalytic reactions using pincer complexes with platinum group metals (Ru, Os, Rh, Ir, Pd, and Pt), specifically in acceptorless dehydrogenation, hydrogenation, hydrogen storage, and cross-coupling reactions. Moreover, this review seeks to highlight the ligand-metal synergy and cooperation present in these systems, and how this enables the development of innovative, versatile, and efficient homogeneous catalysts that outperform known compounds, thereby contributing to greener chemical processes.
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