Synthesis of a CCNC-Silica-Graphene Oxide Porous Monolith for Efficient Copper Ion Removal

Heavy metal contamination in water, predominantly from copper (Cu(II)) ions, poses substantial risks to human and environmental health. This study developed a novel, robust adsorbent known as a carboxylate cellulose nanocrystal-silica-graphene oxide hybrid composite porous monolith, which effectively removes Cu(II) from water in a rapid manner. Carboxylate cellulose nanocrystals with enhanced metal-binding properties were synthesized from cellulose extracted from sugarcane bagasse, a significant agricultural byproduct. The porous monolith was synthesized through the combination of carboxylate cellulose nanocrystals, tetraethyl orthosilicate (TEOS), and graphene oxide, utilizing a sol-gel method. The efficacy of the synthesis was confirmed using Fourier-Transform Infra-red (FTIR), X-ray diffraction (XRD), thermogravimetric analysis (TGA), scanning electron microscope (SEM), and Brunauer-Emmett-Teller (BET) analyses. The material exhibited a highly porous mesoporous structure with a surface area of 512 m²/g, signifying a significant enhancement. Batch adsorption experiments under optimal conditions (pH = 5.5, contact time = 240 min, initial concentration = 200 mg/L) demonstrated a high experimental adsorption capacity of 172 mg/g for Cu(II). The adsorption process was best described by the Langmuir isotherm model, which yielded a theoretical maximum capacity (q_m) of 172 mg/g, and the pseudo-second-order kinetic model, confirming monolayer coverage and chemisorption as the rate-limiting step. Thermodynamic analyses demonstrate that the process is both spontaneous and exothermic. The porous monolith demonstrates the capability for multiple uses, maintaining over 70% efficiency after five cycles. The findings indicate that the carboxylate cellulose nanocrystal-silica-graphene oxide hybrid composite porous monolith is an efficient and robust method for the remediation of copper-contaminated water.