Novel Al-Ce-C-O-Mg Grain Refiners with Superior Efficiency and Mechanical Properties Enhancement for AZ91 Alloys

Grain refinement represents a critical approach in optimizing the as-cast microstructure of magnesium alloys, playing a pivotal role in the development of high-performance magnesium alloys. In the present research, a novel Al-Ce-C-O-Mg grain refiner was fabricated using an innovative rolling-assisted process, and the influence of the grain refiner on the grain size evolution of as-cast AZ91 alloy was systematically examined. The Al-Ce-C-O-Mg grain refiner prepared by the rolling-assisted process contains two types of effective refining particles-MgAl₂O₄ and Al₄C₃. These particles can act as potent nucleation sites for α-Mg in the melt, promoting efficient nucleation and achieving significant grain refinement. By adding 1.0 wt.% of the Al-Ce-C-O-Mg grain refiner to the AZ91 alloy, the grain size of the original AZ91 alloy was reduced by 73%. Moreover, adding a refiner facilitated the transformation of the coarse β-Mg₁₇Al₁₂ phase morphologies into a more uniformly distributed and dispersed form. The addition of 1.0 wt.% Al-Ce-C-O-Mg grain refiner to the AZ91 alloy resulted in significant improvements in its mechanical properties. The ultimate tensile strength (UTS), yield strength (YS), and elongation (EL) increased from 158 MPa, 104 MPa, and 3.9% to 203 MPa, 121 MPa, and 6.3%, respectively. The grain refiner developed in this study demonstrates promising potential for application in Mg alloys.