Counter-propagating entangled photon pairs from monolayer GaSe

Non-phase-matched spontaneous parametric down-conversion (SPDC) in atomically thin materials provides new degrees of freedom and enhanced quantum information capacity compared to conventional phase-matched sources. These systems emerged as promising platforms for quantum computing, communication, and imaging, with the potential to support higher-order nonlinear processes. However, direct observation of photon-pair emission from a monolayer has remained experimentally challenging. In this work, we theoretically modeled SPDC emission across the full angular space from a monolayer GaSe film and experimentally validated the model through measurements of both co- and counter-propagating photon pairs. We demonstrated two-photon quantum correlations in the telecom C-band from a monolayer SPDC source. The spatially symmetric, broadband emission predicted by theory was confirmed experimentally. Furthermore, we observed high-fidelity Bell states in the counter-propagating configuration. Our results revealed the emission characteristics of SPDC in the deeply subwavelength, non-phase-matched regime, and introduced atomically thin, counter-propagating SPDC as a scalable and integrable platform for programmable quantum state generation, extendable via moiré superlattice engineering.