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Complex transition pathways in boiling and cavitation.

M Gallo1, F Occhioni1, F Magaletti1

  • 1Department of Mechanical and Aerospace Engineering, Sapienza University of Rome, via Eudossiana 18, 00184 Rome, Italy.

Journal of Fluid Mechanics
|November 3, 2025

View abstract on PubMed

Summary
This summary is machine-generated.

Investigating vapour bubble nucleation in metastable liquids, this study reveals pathways deviate from classical theory. It introduces a new method to calculate nucleation times, highlighting surface wettability

Keywords:
boilingbubblecavitationdiffuse interfacefluctuating hydrodynamicsnucleationthermal fluctuations.

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Area of Science:

  • Fluid dynamics
  • Thermodynamics
  • Computational physics

Background:

  • Classical nucleation theory often oversimplifies complex phase transitions.
  • Understanding vapour bubble nucleation is crucial for various physical and chemical processes.

Purpose of the Study:

  • To investigate vapour bubble nucleation pathways and times in metastable liquids.
  • To develop a novel method for calculating nucleation times using hydrodynamics.
  • To analyze the impact of surface wettability on heterogeneous nucleation.

Main Methods:

  • Combining Navier-Stokes-Korteweg dynamics with rare event techniques.
  • Utilizing long-wavelength density fluctuations as a key nucleation driver.
  • Inferring diffusion coefficients from hydrodynamic data.

Main Results:

  • Nucleation pathways deviate from classical predictions; bubble volume is insufficient as a reaction coordinate.
  • Surface wettability significantly impacts heterogeneous nucleation, with homogeneous nucleation observed on moderately hydrophilic surfaces.
  • Hydrophobic surfaces accelerate the spinodal decomposition process.

Conclusions:

  • The proposed method accurately predicts nucleation times and reveals non-trivial effects of surface properties.
  • The approach offers a general framework for studying complex nucleation phenomena in various fluids and geometries.
  • Findings challenge classical theories and align with atomistic simulation results.