Jove
Visualize
Contact Us
JoVE
x logofacebook logolinkedin logoyoutube logo
ABOUT JoVE
OverviewLeadershipBlogJoVE Help Center
AUTHORS
Publishing ProcessEditorial BoardScope & PoliciesPeer ReviewFAQSubmit
LIBRARIANS
TestimonialsSubscriptionsAccessResourcesLibrary Advisory BoardFAQ
RESEARCH
JoVE JournalMethods CollectionsJoVE Encyclopedia of ExperimentsArchive
EDUCATION
JoVE CoreJoVE BusinessJoVE Science EducationJoVE Lab ManualFaculty Resource CenterFaculty Site
Terms & Conditions of Use
Privacy Policy
Policies

Related Concept Videos

Anionic Chain-Growth Polymerization: Overview01:20

Anionic Chain-Growth Polymerization: Overview

2.5K
The polymerization process that involves carbanion as an intermediate is called anionic polymerization. It is also a type of addition or chain-growth polymerization. Anionic polymerization gets initiated by a strong nucleophile such as an organolithium or a Grignard reagent. The most commonly used initiator for anionic polymerization is butyl lithium. Monomers involved in anionic polymerization must possess a vinyl group bonded to one or two electron-withdrawing groups. For instance,...
2.5K
Olefin Metathesis Polymerization: Acyclic Diene Metathesis (ADMET)00:53

Olefin Metathesis Polymerization: Acyclic Diene Metathesis (ADMET)

2.2K
Acyclic diene metathesis polymerization or ADMET polymerization involves cross-metathesis of terminal dienes, such as 1,8-nonadiene, to give linear unsaturated polymer and ethylene. As ADMET is a reversible process, the formed ethylene gas must be removed from the reaction mixture to complete the polymerization process.
Similar to cross-metathesis, ADMET also involves the formation of metallacyclobutane intermediate by [2+2] cycloaddition of one of the double bonds of a terminal diene with...
2.2K
Metal-Ligand Bonds02:51

Metal-Ligand Bonds

23.9K
The hemoglobin in the blood, the chlorophyll in green plants, vitamin B-12, and the catalyst used in the manufacture of polyethylene all contain coordination compounds. Ions of the metals, especially the transition metals, are likely to form complexes.
In these complexes, transition metals form coordinate covalent bonds, a kind of Lewis acid-base interaction in which both of the electrons in the bond are contributed by a donor (Lewis base) to an electron acceptor (Lewis acid). The Lewis acid in...
23.9K
Properties of Organometallic Compounds01:23

Properties of Organometallic Compounds

1.6K
Organometallic compounds are compounds that contain a carbon–metal bond. Carbon belongs to an organyl group like alkyl, aryl, allyl, or benzyl groups. The metal can be from Group I or Group II of the periodic table, a transition metal, or a semimetal.
1.6K

You might also read

Related Articles

Articles linked to this work by shared authors, journal, and citation graph.

Sort by
Same author

Metal-organic framework adhesives with exceptionally high heat resistance.

Science and technology of advanced materials·2024
Same author

Spontaneous differentiation of human induced pluripotent stem cells to odorant-responsive olfactory sensory neurons.

Biochemical and biophysical research communications·2024
Same author

Self-Assembled Molecular Fibers Aligned by Compression in Water.

Small (Weinheim an der Bergstrasse, Germany)·2024
Same author

Battery deactivation with redox shuttles for safe and efficient recycling.

Scientific reports·2024
Same author

Sintering Metal-Organic Framework Gels for Application as Structural Adhesives.

Small (Weinheim an der Bergstrasse, Germany)·2023
Same author

Direct Sintering Behavior of Metal Organic Frameworks/Coordination Polymers.

ACS omega·2023

Related Experiment Video

Updated: Jan 12, 2026

Author Spotlight: Exploring Self-Assembled MOF-Polymer Composites
06:48

Author Spotlight: Exploring Self-Assembled MOF-Polymer Composites

Published on: June 14, 2024

2.5K

Dismantlable adhesive using coordination polymer/metal organic framework.

Mitsutaro Umehara1, Izuru Miyazaki2, Akitoshi Suzumura2

  • 1Toyota Central R&D Labs., Inc, Nagakute, Aichi, Japan. umehara@mosk.tytlabs.co.jp.

Scientific Reports
|November 3, 2025
PubMed
Summary

Researchers developed meltable metal-organic frameworks and coordination polymers (MOFs/CPs) as dismantlable adhesives. One material, ZPI, showed high shear strength and could be disassembled in water, highlighting its potential for mild condition applications.

Keywords:
AdhesiveCoordination polymerDismantlable adhesiveMOFMetal organic framework

More Related Videos

Synthesis and Characterization of Functionalized Metal-organic Frameworks
11:27

Synthesis and Characterization of Functionalized Metal-organic Frameworks

Published on: September 5, 2014

49.0K
Surface Functionalization of Metal-Organic Frameworks for Improved Moisture Resistance
08:12

Surface Functionalization of Metal-Organic Frameworks for Improved Moisture Resistance

Published on: September 5, 2018

16.5K

Related Experiment Videos

Last Updated: Jan 12, 2026

Author Spotlight: Exploring Self-Assembled MOF-Polymer Composites
06:48

Author Spotlight: Exploring Self-Assembled MOF-Polymer Composites

Published on: June 14, 2024

2.5K
Synthesis and Characterization of Functionalized Metal-organic Frameworks
11:27

Synthesis and Characterization of Functionalized Metal-organic Frameworks

Published on: September 5, 2014

49.0K
Surface Functionalization of Metal-Organic Frameworks for Improved Moisture Resistance
08:12

Surface Functionalization of Metal-Organic Frameworks for Improved Moisture Resistance

Published on: September 5, 2018

16.5K

Area of Science:

  • Materials Science
  • Chemistry

Background:

  • Traditional adhesives often require harsh conditions for removal, leading to substrate damage.
  • Development of environmentally friendly and easily removable adhesives is crucial for sustainable manufacturing and repair.

Purpose of the Study:

  • To investigate meltable metal-organic frameworks and coordination polymers (MOFs/CPs) as dismantlable adhesives.
  • To evaluate the adhesive properties and disassembly characteristics of synthesized MOF/CP materials.

Main Methods:

  • Synthesis of three MOF/CP materials.
  • Melting and application of MOF/CPs onto copper substrates.
  • Evaluation of shear bonding strength and disassembly via water immersion.

Main Results:

  • One MOF/CP, [Zn(HPO4)(H2PO4)2](H2Im)2 (ZPI), demonstrated high shear strength of approximately 10 MPa.
  • ZPI-bonded joints exhibited significant bond strength reduction after one hour in room temperature water.
  • Manual disassembly of ZPI-bonded joints was achievable under mild conditions.

Conclusions:

  • Meltable MOF/CPs, particularly ZPI, show promise as high-strength, dismantlable adhesives.
  • ZPI functions effectively under mild disassembly conditions (room temperature water).
  • This research opens avenues for developing sustainable and easily repairable adhesive systems.